Structure of Adamanzanes (abbreviated Adz) are compounds containing four atoms linked by (analogous to with nitrogen at the branched position). Often coordinated to a central ligand, the nitrogens occupy the vertices of a, with potentially four faces and six edges, with the carbon chains running approximately along the edges. They can have a 'bowl' or 'cage' structure, with varying lengths or omission of the carbon chains. In the nomenclature of Springborg et al. (1996) these can be described according to the number of chains of specified length: thus, for example, [1 4.2 2]adz is 1,3,6,8-tetraazatricyclo[4.4.1.13,8]-dodecane, a compound which contains four one-carbon chains and two two-carbon chains linking the nitrogens. 3 6adamanzane has found a special use in the preparation of 'inverse ', a compound in which Na − and H + ions coexist, due to the ability of the adamanzane to encapsulate the H + and render it kinetically inert to react with the Na −. References [ ].

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